President Obama signed three executive orders today making it easier for employees to organize labor unions. It marks a change in policy from the Bush Administration. The executive orders are available in either PDF or HTML format from the GPO Access website.

Obama moves to reverse Bush's labor practices -- NY Times

The executive orders will be published in both the Federal Register and the Weekly Compilation of Presidential Documents.  As of 11:16 PST, they were not yet available on the site.  Check the daily version of the Federal Register later today.  Alternatively, the White House website publishes executive orders.